Toluene diisocyanate

  • TDI (preparation of polyurethane Flexible foams, prepolymers and elastomers)
  • TDI (preparation of polyurethane Flexible foams, prepolymers and elastomers)
    Lupranate® T-80 Ex Korea is an isomer mixture of 80 % 2,4- and 20 % 2,6-toluene diisocyanate (TDI).

    Application

    Lupranate® T-80 Ex Korea is used principally for the manufacture of polyurethane flexible foams for the furniture and automotive industries. It is also used for the production of polyurethane paints, adhesives and textile coatings


  • TYPICAL COMPONENT PROPERTIES
    Properties Unit Value Test Method
    Appearance - Colorless liquid -
    Color Pt/Co max. 10 HBUS-E-7028
    Purity g/100g min. 99.5 HBUS-E-7022
    NCO content wt.% 48.3 EN 14896
    2,4-Isomer g/100g 79 ~ 81 HBUS-E-7024
    Acidity as HCI mg/kg max. 20HBUS-E-7011
    Hydrolysable Chlorine mg/kg max. 80 HBUS-E-7010
    Viscosity at 25°C mPa.s 3 DIN 51 550/53 018
    Density at 25°C g/㎤ 1.22 DIN 51 757
  • DELIVERY
    The delivery is by tankers and in non-returnable drums. If delivered in road tankers, temperature during transport should be maintained between 20°C and 40°C. If delivered in drums, temperature should not fall below crystallization point. Exposure to intensive sunlight should be avoided.
  • STORAGE

    Lupranate® T-80 Ex Korea must be protected from moisture. Oxygen and UV-light cause discoloration which normally does not affect the processing of the material. The recommended storage temperature is between 20°C and 40°C. Under these conditions and if moisture and oxygen are excluded, Lupranate® T-80 Ex Korea can be stored for at least 18 months. Drums must be kept airtight. Storage tanks should be blanketed with nitrogen. Storage at higher temperature can lead to discoloration and to a formation of solids. These solids cannot be dissolved by heating. Storage for longer periods under + 15°C can lead to crystallization. Crystallized material must be melted out by short term heating in a hot air oven. Product temperature must not exceed 40°C. Local overheating must be avoided, as Lupranate® T-80 Ex Korea will decompose with formation of gas at temperatures above 250 °C. Rolling of the drums in a hot air oven is the recommended method of dissolving the crystals. After melting out, the contents of the drum must be thoroughly mixed.

  • Safety advice and environmental protection

    Labelling, transportation, storage, processing, waste treatment and disposal must comply with nation regulations. Occupational exposure limits are to be observed. Lupranate® T-80 Ex Korea is classified as very toxic by inhalation. It is irritating to the eyes, respiratory system and skin. It may cause sensitization by inhalation and skin contact. Lupranate® T-80 Ex Korea is classified as a category 3 carcinogen (i.e. a substance which causes concern for man owing to possible carcinogenic effects in animal experiments). Lupranate® T-80 Ex Korea is harmful to aquatic organisms and may cause long-term adverse effects in the aquatic environment. Before processing the product we recommend reading the safety data sheet. For further information consult our Technical information “Safety and Precautionary Measures for the Processing of Polyurethane Systems”. In order to avoid accidents the residual product in the drums must be handled with care. Any water or moisture which is allowed to enter the drum will react with Lupranate® T-80 Ex Korea and release carbon dioxide. Unless action is taken to prevent moisture entry or gas entrapment, the drums will become pressurized and could rupture. If it is intended to use BASF isocyanate materials for the manufacture of consumer goods (e.g. products which will come into contact with foodstuffs or with the skin, toy, etc.) or medical products, national and international regulations have to be observed. We recommend contacting our Sales and our Ecology and Product Safety departments.

  • Disposal of Drums
    Residue of isocyanate remaining in drums must be neutralized. For this purpose, we would recommend that the drums be filled, if possible outdoors, with water containing 0.1% of detergents. The drums should then be allowed to stand with the bunghole open for at least eight days, in which time the isocyanates will be converted to polyurea. This harmless product of the reaction is a solid and may adhere tenaciously to the bottom, lid and sides of the drums. After decontamination and cleaning, the drums may be reused, but under no circumstances for storing foodstuffs